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In the study reported here the combustion and emission characteristics of a heavy duty six-cylinder diesel engine fuelled with dimethyl ether (DME) of chemical grade and DME with small and varying amounts of methanol and/or water were experimentally investigated. In addition, the size distribution of emitted particles and selected unregulated emissions were sampled. Methanol and water additions had a very limited effect on emissions, but affected the combustion processes in a way that accentuated the premixed combustion and thus caused more energy to be released early in the cycle. At high load, however, the effect was reversed, due to the lack of distinct premixed combustion. The results confirm that DME combustion does not generate any accumulation mode particles. The particles that are detected are smaller than the soot size range and do not occur in greater numbers than those from a diesel engine in the corresponding size range.

The CFD model, based on the LANL KIVA-3 computer code, modified to account for the multi-step dimethyl ether, DME/air, oxidation chemistry, was developed and used to study the neat DME combustion dynamics in a constant volume at Diesel-like conditions and in the Volvo AH10A245DI Diesel engine. Constant volume simulations confirm high ignition quality of neat DME in air. The results of engine modeling illustrate that the injection schedule used for Diesel fuel is not optimal for DME. Surprisingly, the positive gain and peak pressure levels comparable with those for Diesel fuel were obtained using an early (∼ -20 ATDC) injection through a nozzle of a larger diameter at reduced injection pressures and velocities (∼150m/s) preventing too rapid spray atomization. At these conditions, combustion heat release has a specific two-stage character with a peak value placed behind the TDC.

This paper depicts the main topics of the experimental investigation on alcohol engine development field, aiming at the engineering targets for the emission levels. The first part of this study was focused on engine design optimization for running on ethanol mixed with poly-ethylene glycol (PEG) as ignition improver. It was shown that some design changes in compression ratio, turbine casing, injector nozzle configuration and exhaust pressure governor (EPG) activation, lead to a better engine thermodynamics and its thermochemistry. The second objective of this study was the investigation of engine performance and emission levels, when the ignition improver diethyl ether (DEE) would be generated on board via catalytically dehydration of ethanol, and used directly as soluble mixture or separately fumigated.

Future demands for improvements in the fuel economy of gasoline passenger car engines will require the development and implementation of advanced combustion strategies, to replace, or combine with the conventional spark ignition strategy. One possible strategy is homogeneous charge compression ignition (HCCI) achieved using negative valve overlap (NVO). However, several issues need to be addressed before this combustion strategy can be fully implemented in a production vehicle, one being to increase the upper load limit. One constraint at high loads is the combustion becoming too rapid, leading to excessive pressure-rise rates and large pressure fluctuations (ringing), causing noise. In this work, efforts were made to reduce these pressure fluctuations by using a late injection during the later part of the compression. A more appropriate acronym than HCCI for such combustion is SCCI (Stratified Charge Compression Ignition).

Further restrictions on NOx emissions and the extension of current driving cycles for passenger car emission regulations to higher load operation in the near future (such as the US06 supplement to the FTP-75 driving cycle) requires attention to low emission combustion concepts in medium to high load regimes. One possibility to reduce NOx emissions is to increase the EGR rate. The combustion temperature-reducing effects of high EGR rates can significantly reduce NO formation, to the point where engine-out NOx emissions approach zero levels. However, engine-out soot emissions typically increase at high EGR levels, due to the reduced soot oxidation rates at reduced combustion temperatures and oxygen concentrations.

DME was tested in a heavy duty diesel engine and in an optically accessible high-temperature and pressure spray chamber in order to investigate and understand the effect of nozzle parameters on emissions, combustion and fuel spray concentration. The engine study clearly showed that smaller nozzle orifices were advantageous from combustion, efficiency and emissions considerations. Heat release analysis and fuel concentration images indicate that smaller orifices result in higher mixing rate between fuel and air due to reductions in the turbulence length scale, which reduce both the magnitude of fuel-rich regions and the steepness of fuel gradients in the spray, which enable more fuel to burn and thereby shorten the combustion duration.

Wall wetting can occur irrespective of combustion concept in diesel engines, e.g. during the compression stroke. This action has been related to engine-out emissions in different ways, and an experimental investigation of impinging diesel sprays is thus made for a standard diesel fuel and a two-component model fuel (IDEA). The experiment was performed at conditions corresponding to those found during the compression stroke in a heavy duty diesel engine. The spray characteristics of two fuels were measured using two different optical methods: a Phase Doppler Particle Analyzer (PDPA) and high-speed imaging. A temperature controlled wall equipped with rapid, coaxial thermocouples was used to record the change in surface temperature from the heat transfer of the impinging sprays.

This paper describes an analysis of the Diesel Oil Surrogate (DOS) model used at Chalmers University (Sweden), including 70 species participating in 310 reactions, and subsequent improvements prompted by the model's systematic tendency to under-predict the combustion intensity in simulations of kinetically-driven combustion modes, e.g. Homogeneous Charged Compression Ignition (HCCI). Key bases of the model are the properties of a model Diesel fuel with the molecular formula C14H28. In the vapor phase, a global reaction decomposes the starting fuel, C14H28, into its constituent components; n-heptane (C7H16) and toluene (C7H8). This global reaction was modified to yield a higher n-heptane:toluene ratio, due to the importance of preserving an n-heptane-like cetane number.

A novel concept of combined hydrogen production and power generation system based on the combustion of aluminum in water is explored. The energy conversion system proposed is potentially able to provide four different energy sources, such us pressurized hydrogen, high temperature steam, heat, and work at the crankshaft on demand, as well as to fully comply with the environment sustainability requirements. Once aluminum oxide layer is removed, the pure aluminum can react with water producing alumina and hydrogen while releasing a significant amount of energy. Thus, the hydrogen can be stored for further use and the steam can be employed for energy generation or work production in a supplementary power system. The process is proved to be self-sustained and to provide a remarkable amount of energy available as work or hydrogen.

It has been previously shown that engine-out soot emissions can be reduced by using Fischer-Tropsch (FT) fuels, due to their lack of aromatics, compared to conventional Diesel fuels. In this investigation the engine-out emissions and fuel consumption parameters of an FT fuel derived from natural gas were compared to those of Swedish low sulfur diesel (MK1) when used in Low Temperature Combustion mode in a single cylinder heavy-duty diesel engine. The effects of varying Needle Opening Pressure (NOP), Charge Air Pressure (CAP) and Exhaust Gas Recirculation (EGR) according to an experimental design on the measured variables were also assessed. CAP and EGR were found to be the most significant factors for the combustion and emission parameters of both fuels. Increases in CAP resulted in lower soot emissions due to enhanced charge mixing, however NOx emissions rose as CAP increased.

The purpose of the investigation presented here was to compare the effects of fuel composition on combustion parameters, emissions and fuel consumption in engine tests and simulations with five fuels: a Diesel-water emulsion, a Diesel-ethanol blend, a Diesel-ethanol blend with EHN (cetane number improver), a Fischer-Tropsch Diesel and an ultra-low sulfur content Diesel. The engine used in the experiments was a light duty, single cylinder, direct injection, common rail Diesel engine equipped with a cylinder head and piston from a Volvo NED5 engine. In tests with each fuel the engine was operated at two load points (3 bar IMEP and 10 bar IMEP), and a pilot-main fuel injection strategy was applied under both load conditions. Data were also obtained from 3-D CFD simulations, using the KIVA code, to compare to the experimental results and to further analyze the effects of water and ethanol on combustion.

The possibilities of operating a direct injection Diesel engine in HCCI combustion mode with early injection of conventional Diesel fuel were investigated. In order to properly phase the combustion process in the cycle and to prevent knock, the geometric compression ratio was reduced from 17.0:1 to 13.4:1 or 11.5:1. Further control of the phasing and combustion rate was achieved with high rates of cooled EGR. The engine used for the experiments was a single cylinder version of a modern passenger car type common rail engine with a displacement of 480 cc. An injector with a small included angle was used to prevent interaction of the spray and the cylinder liner. In order to create a homogeneous mixture, the fuel was injected by multiple short injections during the compression stroke. The low knock resistance of the Diesel fuel limited the operating conditions to low loads. Compared to conventional Diesel combustion, the NOx emissions were dramatically reduced.

The influence of ethanol content in gasoline on speciated emissions from a direct injection stratified charge (DISC) SI engine is assessed. The engine tested is a commercial DISC one that has a wall guided combustion system. The emissions were analyzed using both Fourier transform infrared (FTIR) spectroscopy and conventional emission measurement equipment. Seven fuels were compared in the study. The first range of fuels was of alkylate type, designed to have 0, 5, 10 and 15 % ethanol in gasoline without changing the evaporation curve. European emissions certification fuel was tested, with and without 5 % ethanol, and finally a specially blended high volatility gasoline was also tested. The measurements were conducted at part-load, where the combustion is in stratified mode. The engine used a series engine control unit (ECU) that regulated the fuel injection, ignition and exhaust gas recirculation (EGR).

Future emission legislation will require substantial reductions of NOx and particulate matter (PM) emissions from diesel engines. The combustion and emission formation in a diesel engine is governed mainly by spray formation and mixing. Important parameters governing these are droplet size, distribution, concentration and injection velocity. Smaller orifices are believed to give smaller droplet size, even with reduced injection pressure, which leads to better fuel atomization, faster evaporation and better mixing. In this paper experiments are performed on a single cylinder heavy-duty direct injection diesel engine with three nozzles of different orifice diameters (Ø0.227 mm, Ø0.130 mm, Ø0.090 mm). Two loads (low and medium) and three speeds were investigated. The test results confirmed a substantial reduction in HC and soot emissions at lower loads for the small orifices.

A single-cylinder engine was operated in HCCI combustion mode with different kinds of commercial fuels. The HCCI combustion was generated by creating a negative valve overlap (early exhaust valve closing combined with late intake valve opening) thus trapping a large amount of residuals (∼ 55%). Fifteen different fuels with high octane numbers were tested six of which were primary reference fuels (PRF's) and nine were commercial fuels or reference fuels. The engine was operated at constant operational parameters (speed/load, valve timing and equivalence ratio, intake air temperature, compression ratio, etc.) changing only the fuel type while the engine was running. Changing the fuel affected the auto-ignition timing, represented by the 50% mass fraction burned location (CA50). However these changes were not consistent with the classical RON and MON numbers, which are measures of the knock resistance of the fuel. Indeed, no correlation was found between CA50 and the RON or MON numbers.

For the application to Gasoline Homogenous Charge Compression Ignition (HCCI) modeling, a multi-zone model was developed. For this purpose, the detailed-chemistry code SENKIN from the CHEMKIN library was modified. In a previous paper, the authors explained how piston motion and a heat transfer model were implemented in the SENKIN code to make it applicable to engine modeling. The single-zone model developed was successfully implemented in the engine cycle simulation code AVL BOOST™. A multi-zone model, including a crevice volume, a quench layer and multiple core zones, is introduced here. A temperature distribution specified over these zones gives this model a wider range of application than the single-zone model, since fuel efficiency, emissions and heat release can now be predicted more accurately. The SENKIN-BOOST multi-zone model predictions are compared with experimental data.

A single cylinder, naturally aspirated, four-stroke and camless (Otto) engine was operated in homogeneous charge compression ignition (HCCI) mode with commercial gasoline. The valve timing could be adjusted during engine operation, which made it possible to optimize the HCCI engine operation for different speed and load points in the part-load regime of a 5-cylinder 2.4 liter engine. Several tests were made with differing combinations of speed and load conditions, while varying the valve timing and the inlet manifold air pressure. Starting with conventional SI combustion, the negative valve overlap was increased until HCCI combustion was obtained. Then the influences of the equivalence ratio and the exhaust valve opening were investigated. With the engine operating on HCCI combustion, unthrottled and without preheating, the exhaust valve opening, the exhaust valve closing and the intake valve closing were optimized next.

Heat transfer to the walls of the combustion chamber is increased by engine knock. In this study the influence of knock onset and knock intensity on the heat flux is investigated by examining over 10 000 individual engine cycles with a varying degree of knock. The heat transfer to the walls was estimated by measuring the combustion chamber wall temperature in an SI engine under knocking conditions. The influence of the air-fuel ratio and the orientation of the oscillating cylinder pressure-relative to the combustion chamber wall-were also investigated. It was found that knock intensities above 0.2 Mpa influenced the heat flux. At knock intensities above 0.6 Mpa, the peak heat flux was 2.5 times higher than for a non-knocking cycle. The direction of the oscillations did not affect the heat transfer.

SI Engine knock is caused by autoignition in the unburnt part of the mixture (end-gas) ahead of the propagating flame. Autoignition of the end-gas occurs when the temperature and pressure exceeds a critical limit when comparatively slow reactions-releasing moderate amounts of heat-transform into ignition and rapid heat release. In this paper the difference in the heat released in the end-gas-by low temperature chemistry-between lean, rich, stochiometric, and stoichiometric mixtures diluted with cooled EGR was examined by measuring the temperature in the end-gas with Dual Broadband Rotational CARS. The measured temperature history was compared with an isentropic temperature calculated from the cylinder pressure trace. The experimentally obtained values for knock onset were compared with results from a two-zone thermodynamic model including detailed chemistry modeling of the end-gas reactions.

Having low aromatic compounds, high cetane rating, higher heat of combustion and almost zero sulphur content, a new paraffinic fuel (NPF), developed by Oroboros AB Sweden, was believed to receive attention as a new alternative fuel. Therefore, further investigation and combustion analyses were conducted in a research single-cylinder diesel engine, where detailed thermodynamic analyses were performed by Burst to File high frequency signal sampling code and by the Dragon software, revealing the real thermochemistry history. The aim of this investigation was an effort to reduce the pollution levels in Santiago de Chile by introducing this new paraffinic fuel (NPF). Experimental results have shown that the NPF fuel has a significant impact not only on the emission levels, but also on other energetic parameters of the engine such as ignition delay, cylinder peak pressure, heat release gradient, indicated efficiency etc.